9FFluorinereactive nonmetal
Atomic weight18.998403163conventional

Fluorine(F)

Fluorine (F) is a reactive nonmetal in period 2 of the periodic table. Its properties reflect its electron configuration and position among neighbouring elements.

reactive nonmetalGroup 17Period 2p-blockgas at STP
Position:Period 2, Group 17, Block p• Grid2:17[He] 2s² 2p⁵

KEY PROPERTIES

Atomic number
9
Atomic weight
18.998403163
Category / Block
reactive nonmetal • p-block
Group / Period
17 / 2
Electron configuration
[He] 2s² 2p⁵
State at STP
gas(STP (0 °C, 100 kPa))

Electron configuration & shells

[He] 2s² 2p⁵

27

Shell model is schematic — see lesson on atomic structure for orbitals. Oxidation states: -1. Common ions: F⁻.

Measured properties

Values at stated conditions; missing data shown as “—”. Radii distinguished by type; densities at stated phase/temperature.

Electronegativity (Pauling)
3.98
First ionization energy
1681 kJ·mol⁻¹ (first ionization, gas phase)
Atomic radius
42 pm (calculated)
Covalent radius
57 pm (covalent)
Van der Waals radius
147 pm (van der Waals)
Density
0.001696 g·cm⁻³ (gas at STP)
Melting point
53.48 K (1 atm)
Boiling point
85.03 K (1 atm)

Standard conditions: 1 atm unless noted. Values with null are not established or not comparable across allotropes. Radii are distinguished by type. Densities at stated phase/temperature.

Isotopes — Fluorine
Mass numberAbundanceStabilityHalf-life
19trace/syntheticstable

Isotopic abundances are natural terrestrial values where applicable; synthetic isotopes shown as trace.

Occurrence & uses

Occurs naturally; abundance and extraction depend on geochemistry. For heavy synthetics (Z > 92), no natural occurrence.

  • Industrial use
  • Laboratory reagent
  • Research

Discovery

Unknown — —

Safety

Elemental fluorine (F₂) is extremely reactive and toxic — specialist handling; fluoride ion hazards differ by compound and concentration. Always use SDS for the exact material.

Reactions involving F

SOURCES

  1. [nist-atomic-weights]nist-atomic-weights (2022)/#nist-atomic-weights
  2. [nist-2022]nist-2022 (2022)/#nist-2022
  3. [iupac-gold]iupac-gold (2022)/#iupac-gold

Last reviewed: 2026-08-22 • Reviewer: dr-example

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