Formula Library

Verified chemistry formulas — each page shows equation, purpose, variables, units, conditions, rearrangements, dimensional check, example, common errors, and related resources. Only published, reviewed formulas appear.

29 published
k = A e^{-E_a/(RT)}

Arrhenius Equation

Temperature dependence of rate constant.

chemical-kinetics
\bar{M}=\sum f_i M_i

Average Atomic Mass

Weighted average isotopic masses by fractional abundance.

atomic-structure
N = n N_A

Avogadro Relation

Relate number of entities to amount via Avogadro constant.

mole-stoichiometry
P_1 V_1 = P_2 V_2

Boyle's Law

Pressure-volume inverse at constant n,T.

gases-gas-laws
q = m c \Delta T

Calorimetry Heat

Heat from mass, specific heat, temperature change.

thermochemistry-thermodynamics
\frac{V_1}{T_1}=\frac{V_2}{T_2}

Charles's Law

Volume-temperature direct at constant P.

gases-gas-laws
\frac{P_1 V_1}{T_1}=\frac{P_2 V_2}{T_2}

Combined Gas Law

Combine Boyle, Charles, Gay-Lussac for constant n.

gases-gas-laws
P_{tot}=\sum P_i,\ P_i = x_i P_{tot}

Dalton's Partial Pressures

Total pressure = sum of partials; partial from mole fraction.

gases-gas-laws
N = N_0 e^{-kt}, \ln\frac{N_0}{N}=kt

Radioactive Decay Law

Amount remaining after time t via exponential decay.

nuclear-chemistry
\rho = \frac{m}{V}

Density

Relate mass and volume to characterize substances.

matter-measurement
c_1 V_1 = c_2 V_2

Dilution Equation

Relate concentrations before and after dilution (moles conserved).

solutions-concentration
\text{ratio}=\frac{\% /M}{smallest}

Empirical Formula Relation

Determine simplest whole-number ratio from percent composition.

mole-stoichiometry
K_c = \frac{[C]^c[D]^d}{[A]^a[B]^b}

Equilibrium Constant Kc

Ratio of product/reactant concentrations at equilibrium.

chemical-equilibrium
m = \frac{Q M}{n F} = \frac{I t M}{n F}

Faraday's Electrolysis

Mass deposited/evolved in electrolysis.

redox-electrochemistry
\Delta G = \Delta H - T\Delta S

Gibbs Energy

Predict spontaneity and maximum non-PV work.

thermochemistry-thermodynamics
t_{1/2}=\frac{\ln 2}{k}

Half-Life (First-Order)

Time for half of nuclei/amount to decay for first-order.

nuclear-chemistry
pH = pK_a + \log\frac{[A^-]}{[HA]}

Henderson–Hasselbalch

pH of buffer from conjugate pair ratio; approximations limited.

acids-bases-buffers
\Delta H_{rxn}=\sum \Delta H_{steps}

Hess's Law

Sum stepwise enthalpies to find overall reaction enthalpy.

thermochemistry-thermodynamics
PV = nRT

Ideal Gas Law

Relate pressure, volume, amount, temperature for an ideal gas.

gases-gas-laws
K_{sp}=[A^+]^a[B^-]^b

Ksp Expression

Solubility product for sparingly soluble salt.

solubility-precipitation
b = \frac{n}{m_{solvent}}

Molality

Concentration per mass solvent, temperature independent.

solutions-concentration
c = \frac{n}{V}

Molarity

Concentration as amount per volume of solution.

solutions-concentration
n = \frac{m}{M}

Moles from Mass

Convert measurable mass to amount of substance.

mole-stoichiometry
E = E^\circ - \frac{RT}{nF}\ln Q

Nernst Equation

Cell potential under nonstandard conditions.

redox-electrochemistry
\%E = \frac{m_E}{m_{tot}} \times 100

Percent Composition

Mass fraction of an element in a compound.

mole-stoichiometry
\%_{yield}=\frac{m_{actual}}{m_{theoretical}}\times100

Percent Yield

Compare actual to theoretical product mass.

mole-stoichiometry
E = h\nu = \frac{hc}{\lambda}

Photon Energy

Energy of photon from frequency or wavelength.

atomic-structure
\text{rate}=k[A]^m[B]^n

Rate Law

Express rate dependence on concentrations with orders.

chemical-kinetics
Q = \frac{[C]^c[D]^d}{[A]^a[B]^b}_{non-eq}

Reaction Quotient Q

Compare current state to equilibrium; predict direction.

chemical-equilibrium

All formulas include purpose, conditions, rearrangements, dimensional check, worked example, and common errors. Linked calculators appear only when real.

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