Dalton's Partial Pressures

Total pressure = sum of partials; partial from mole fraction.

gases-gas-lawsReviewed 21/8/2026
On this page
  1. Equation
  2. Variables
  3. Conditions
  4. Example
  5. Common errors
  6. Sources

Equation and purpose

Total pressure = sum of partials; partial from mole fraction.

Dalton's Partial Pressures
\[P_{tot}=\sum P_i,\ P_i = x_i P_{tot}\]

Total pressure = sum of partials; partial from mole fraction.

REARRANGEMENTS
$x_i=P_i/P_{tot}$

Dimensional check: atm ✓

Variables and units

VARIABLES
SymbolQuantityUnitNotes
P_totP_tot
P_iP_i
x_ix_i

Conditions and limitations

Ideal gas mixture; non-reacting gases.

Worked example

0.2 O₂ at 1 atm total →0.2 atm partial.

Dalton’s Partial Pressures

Total pressure = sum of partials; partial from mole fraction.

Equation

Ptot=Pi, Pi=xiPtotP_{tot}=\sum P_i,\ P_i = x_i P_{tot}

Inline: $P_{tot}=\sum P_i,\ P_i = x_i P_{tot}$$

Variables

SymbolQuantityUnitNotes
PtotP_tottotal pressureatm
PiP_ipartial pressureatm
xix_imole fraction

Conditions and limitations

Ideal gas mixture; non-reacting gases.

Rearrangements

xi=Pi/Ptotx_i=P_i/P_{tot}

Dimensional check: atm ✓

Worked example

0.2 O₂ at 1 atm total →0.2 atm partial.

Steps: write equation → substitute with units → check dimensional consistency → report with correct significant figures.

Common errors

  • Confusing mole fraction with mass fraction

Sources

  • NIST Physical Constants 2022 — CODATA.

Reviewed 2026-08-21 by Editorial Team; due 2027-08-21.

Common errors

  • Confusing mole fraction with mass fraction
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Reviewed August 21, 2026

SOURCES

  1. [nist-2022]NIST Physical Constants 2022 (2022). NISThttps://physics.nist.gov/constants
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